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Matthew Sinclair

PhD: 2017 – 2022

One-electron chemistry of palladium, platinum, and gold bis(phosphine) complexes

Linkedin: ORCID:

Publications

7. M. J. G. Sinclair, M.-E. Moret, L. A. Wilkinson, and A. B. Chaplin. Gold(I) Phosphine/Phosphido-Borohydride Complexes. .
6. M. J. G. Sinclair, N. Roig, N. Tsoureas, M. Alonso, and A. B. Chaplin. Synthesis and Characterisation of {PdNO}¹⁰ Pincer Complexes. .
5. M. J. G. Sinclair, N. Roig, M. R. Gyton, N. Tsoureas, F. G. N. Cloke, M. Alonso, and A. B. Chaplin. T-Shaped Palladium and Platinum {MNO}¹⁰ Nitrosyl Complexes. .
4. T. Krämer, M. R. Gyton, I. Bustos, M. J. G. Sinclair, S.-y. Tan, C. J. Wedge, S. A. Macgregor and A. B. Chaplin. Stability and C–H Bond Activation Reactions of Palladium(I) and Platinum(I) Metalloradicals: Carbon-to-Metal H-Atom Transfer and an Organometallic Radical Rebound Mechanism..
3. M. J. G. Sinclair and A. B. Chaplin. Heterolytic carbon–iodine bond cleavage by a palladium(I) metalloradical. .
2. M. J. G. Sinclair and A. B. Chaplin. Oxidative ring expansion of a low-coordinate palladacycle: synthesis of a robust T-shaped alkylpalladium(II) complex. .
1. Q. Simpson, M. J. G. Sinclair, D. W. Lupton, A. B. Chaplin and J. F. Hooper. Oxidative Cross-Coupling of Boron and Antimony Nucleophiles via Palladium(I). .